Reversible intercyclobutadiene haptotropism in cyclopentadienylcobalt linear [4]phenylene.
نویسندگان
چکیده
Cyclopentadienylcobalt complexes of linear [4]phenylene undergo thermally reversible photoinduced metallahaptotropism between the inner and outer cyclobutadiene ring.
منابع مشابه
Theoretical investigation on switchable second-order nonlinear optical (NLO) properties of novel cyclopentadienylcobalt linear [4]phenylene complexes
As a kind of novel organometallic complexes, the cyclopentadienylcobalt (CpCo) linear [4]phenylene complexes (4 = number of benzene rings) display efficient switchable nonlinear optical (NLO) response when CpCo reversibly migrates along the linear [4]phenylene triggered by heating or lighting. In this paper, the second-order NLO properties for CpCo linear [4]phenylene complexes were calculated ...
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عنوان ژورنال:
- Chemical communications
دوره 47 32 شماره
صفحات -
تاریخ انتشار 2011